School of Materials Science and Engineering
Integrated Research Building
010-82529331

Publications

2022

47. Transition-metal Free Visible Light Photoredox-catalyzed Remote C(sp3)-H Borylation Enabled by 1,5-Hydrogen Atom Transfer

Beiqi Sun, Wenke Li, Qianyi Liu, Gaoge Zhang and Fanyang Mo*

ChemRxiv preprint 2022 2022-11-27

46. Retention Time Prediction for Chromatographic Enantioseparation by Quantile Geometry-enhanced Graph Neural Network

Hao Xu, Jinglong Lin, Dongxiao Zhang* and Fanyang Mo*

arXiv preprint 2022 2022-11-8

45. High-throughput automated platform for thin layer chromatography analysis

Hao Xu, Dongxiao Zhang* and Fanyang Mo*

Star Protocols 2022, accepted. 2022-11-1

44. High-throughput discovery of chemical structure-polarity relationships combining automation and machine learning techniques

Hao Xu#, Jinglong Lin#, Qianyi Liu, Yuntian Chen, Jianning Zhang, Yang Yang, Michael C. Young, Yan Xu, Dongxiao Zhang* and Fanyang Mo*

Chem 2022, in press. 2022-08-12

A video associated with this work: English version, Chinese version

43. Thermodynamic analysis of a novel multi-target temperature transcritical CO2 ejector-expansion refrigeration cycle with vapor-injection

Min-Qiang Zeng, Qiu-Yun Zheng, Xuelai Zhang, Fan-Yang Mo and Xin-Rong Zhang*

Energy 2022, 125016. 2022-08-05

42. Precise electrical gating of the single-molecule Mizoroki-Heck reaction

Lei Zhang, Chen Yang, Chenxi Lu, Xingxing Li, Yilin Guo, Jianning Zhang, Jinglong Lin, Zhizhou Li, Chuancheng Jia, Jinlong Yang, K. N. Houk*, Fanyang Mo* and Xuefeng Guo*

Nat. Commun. 2022, 13, 4552. 2022-06-20

41. 芳基锡烷的合成研究进展

岳广禄, 魏婧瑶, 邱頔*, 莫凡洋*

化学学报 2022, 80, 956-969. 2022-05-10

40. Thermodynamic analysis of the effect of internal heat exchanger on the dual-ejector transcritical CO2 cycle for low-temperature refrigeration

Min-Qiang Zeng, Xue-Lai Zhang, Fan-Yang Mo and Xin-Rong Zhang*

Int. J. Energy Res. 2022, 46, 12702-12721. 2022-05-04

39. 如何拥抱智能时代——以化学学科为例

林京龙, 刘谦益, 莫凡洋*

中国科学: 化学 2022, xx, xx-xx. Mar 14 2022

38. Synthesis of Alkylboronic Esters from Alkyl Iodides

Qianyi Liu, Hao Liang, Shangyong Zhou, Lei Zhang, Jianxin Yang, Yunxing Yin, Yang Yang, Di Qiu and Fanyang Mo*

Checked by Jordan Thompson and Sarah Reisman @ Caltech

Org. Syn. 2022, 99, 15-28. Mar 10 2022

37. Transition Metal Free Stannylation of Alkyl Halides: the Rapid Synthesis of Alkyltrimethylstannanes

Songyi Li, Chang Lian, Guanglu Yue, Jianning Zhang, Di Qiu* and Fanyang Mo*

J. Org. Chem. 2022, 87, 4291–4297. Mar 9 2022

36. Electrocatalytic Oxidative Hydrofunctionalization Reactions of Alkenes via Co(II/III/IV) Cycle

Fan Yang, Yi-Chen Nie, Han-Yuan Liu, Lei Zhang, Fanyang Mo and Rong Zhu*

ACS Catal. 2022, 12, 2132–2137. Jan.27. 2022

35. Accurate Single-Molecule Kinetic Isotope Effects

Yilin Guo, Chen Yang, Huiping Li, Lei Zhang, Shuyao Zhou, Xin Zhu, Huanyan Fu, Zhizhou Li, Zhirong Liu, Chuancheng Jia, Zitong Liu*, Wenguang Zhu*, Fanyang Mo*, Deqing Zhang*, and Xuefeng Guo*

J. Am. Chem. Soc. 2022, 144, 3146–3153. Jan 17 2022

2021

34. Carbon Capture, Utilization & Storage: A General Overview

Dongxiao Zhang,* Ruqiang Zou, Xidong Wang, Jin Liu and Fanyang Mo

Climate Mitigation and Adaptation in China 2022 Pages 61-107. Nov 12 2021


33. Unveiling the full reaction path of the Suzuki-Miyaura cross-coupling in a single molecule junction

Chen Yang, Lei Zhang, Chenxi Lu, Shuyao Zhou, Xingxing Li, Yanwei Li, Yang Yang, Yu Li, Zhirong Liu, Jinlong Yang, K. N. Houk,* Fanyang Mo,* and Xuefeng Guo*

Nat. Nanotechnol. 2021, 16, 1214–1223. Sep 2 2021

Highlighted by Nat. Nanotechnol. 2021, 16, 1176–1177.


32. Single-Molecule Electrical Spectroscopy of Organocatalysis

Chen Yang, Lei Zhang, Huiping Li, Yilin Guo, Chuancheng Jia, Wenguang Zhu*, Fanyang Mo* and Xuefeng Guo*

Matter 2021, 4, 2874–2885. Jun 18 2021

Highlighted by Chem. 2021, 9, 2275-2276.


31. Suzuki-Miyaura偶联反应机理研究进展

张雷, 杨晨, 郭雪峰*, 莫凡洋*

Chin. J. Org. Chem. 2021, 41, 2874–2885. Jun 1 2021


30. Transition metal- and photo-free radical borylation of alkyl bromides and iodides by silane

Beiqi Sun, Sihan Zheng and Fanyang Mo*

Chem. Commun. 2021, 57, 5674–5677. Apr 29 2021


29. Recent Development of Aryl Diazonium Chemistry for the Derivatization of Aromatic Compounds

Fanyang Mo,* Di Qiu, Lei Zhang and Jianbo Wang*

Chem. Rev. 2021, 121, 5741-5829. Apr 10 2021


28. Photo-induced radical borylation of hemiacetals via C−C bond cleavage

Qianyi, Liu, Jianning Zhang, Lei Zhang and Fanyang Mo*

Tetrahedron 2021, 80, 131867. Jan 19 2021


27. An accurate, high-speed, portable bifunctional electrical detector for COVID-19

Guojun Ke, Dingkai Su, Yu Li, Yu Zhao, Honggang Wang, Wanjian Liu, Man Li, Zhiting Yang, Fang Xiao, Yao Yuan, Fei Huang,* Fanyang Mo,* Peng Wang,* Xuefeng Guo*

SCIENCE CHINA Materials 2021, 64, 739-747. Nov 27 2020


2020

26. Anodic Oxidation Triggered Divergent 1,2- and 1,4-Group Transfer Reactions of β-Hydroxycarboxylic Acids Enabled by Electrochemical Regulation

Zhenxing Zhang, Lei Zhang, Xianhao Zhang, Jianxin Yang, Yunxing Yin, Yangye Jiang, Cheng-Chu Zeng, Gang Lu, Yang Yang and Fanyang Mo*

Chem. Sci. 2020, 11, 12021-12028. Sep 28 2020


25. 基于自由基机理的有机硼酯化反应

刘谦益, 张雷, 莫凡洋*

化学学报 2020, 78, 1297-1308. Aug 1 2020


24. Cuprous halide catalysed carboxylation of alkenyl boronic acids and alkenyl boronic acid pinacol esters with CO2

Junting Hong, Onkar S. Nayal and Fanyang Mo*

Eur. J. Org. Chem. 2020, 2813-2818. Apr 16 2020


23. Discussion Addendum for: Synthesis of Arylboronic Pinacol Esters from Corresponding Arylamines

Fanyang Mo, Di Qiu and Jianbo Wang*

Org. Synth. 2020, 97, 1-11. Aug 1 2020


22. Electro-catalytic oxidative transformation of organic acids for carbon-heteroatom and sulfur-heteroatom bond formation

Man Li, Junting Hong, Wei Xiao, Yang Yang, Di Qiu and Fanyang Mo*

ChemSusChem 2020, 13, 1661-1687. Dec 5 2019


2019

21. Cu-catalysed carboxylation of aryl boronic acids with CO2

Onkar S. Nayal, Junting Hong, Yang Yang and Fanyang Mo*

Org. Chem. Front. 2019, 6, 3673-3677. Sep 23 2019


20. Modification of TiO2 Nanoparticles with Organodiboron Molecules Inducing Stable Surface Ti3+ Complex

Yang Cao, Peng Zhou, Yongguang Tu, Zheng Liu, Bo-Wei Dong, Aryan Azad, Dongge Ma, Dong Wang, Xu Zhang, Yang Yang, Shang-Da Jiang, Rui Zhu, Shaojun Guo, Fanyang Mo* and Wanhong Ma

iScience 2019, 20, 195-204. Sep 18 2019


19. Zn+-O- dual-spin surface states formation by modification of ZnO nanoparticles with diboron compounds

Yang Cao, Yongguang Tu, Peng Zhou, Jianning Zhang, Yuchen Deng, Biao Kong, Xu Zhang, Shaojun Guo, Rui Zhu, Ding Ma, Yang Yang and Fanyang Mo*

Langmuir 2019, 35, 14173-14179. Aug 14 2019


18. Energy Level Modulation in Diboron Modified SnO2 for High Efficiency Perovskite Solar Cells

Nengxu Li, Xiuxiu Niu, Fengtao Pei, Huifen Liu, Yang Cao, Yuquan Liu, Haipeng Xie, Yongli Gao, Qi Chen, Fanyang Mo* and Huanping Zhou*

Sol. RRL 2019, 3, 201900217. Jul 13 2019


17. Transition-Metal-Free Borylation of Alkyl Iodides via a Radical Mechanism

Qianyi Liu, Junting Hong, Beiqi Sun, Guangcan Bai, Feng Li, Guoquan Liu, Yang Yang and Fanyang Mo*

Org. Lett. 2019, 21, 6597-6602. Jun 25 2019


16. Electrochemical Radical Borylation of Aryl Iodides

Junting Hong, Qianyi Liu, Feng Li, Guangcan Bai, Guoquan Liu, Man Li, Onkar S. Nayal, Xuefeng Fu and Fanyang Mo*

Chin. J. Chem. 2019, 37, 347-351. Jun 25 2019


15. Mn-Mediated Electrochemical Trifluoromethylation/C(sp2)–H Functionalization Cascade for the Synthesis of Azaheterocycles

Zhenxing Zhang, Lei Zhang, Yang Cao, Feng Li, Guangcan Bai, Guoquan Liu, Yang Yang and Fanyang Mo*

Org. Lett. 2019, 21, 762-766. Jan 23 2019


14. C–H Bond Carboxylation with Carbon Dioxide

Junting Hong, Man Li, Jianning Zhang, Beiqi Sun and Fanyang Mo*

ChemSusChem 2019, 12, 6-39. Nov 1 2018


2018

13. Diboron-Assisted Interfacial Defect Control Strategy for Highly Efficient Planar Perovskite Solar Cells

Yongguang Tu, Xiaoyu Yang, Rui Su, Deying Luo, Yang Cao, Lichen Zhao, Tanghao Liu, Wenqiang Yang, Yifei Zhang, Zhaojian Xu, Quanzhen Liu, Jihuai Wu, Qihuang Gong, Fanyang Mo and Rui Zhu*

Adv. Mater. 2018, 1805085. Oct 9 2018

12. A General Electrochemical Strategy for Sandmeyer Reaction

Qianyi Liu, Beiqi Sun, Zheng Liu, Yi Kao, Bo-Wei Dong, Shang-Da Jiang, Feng Li, Guoquan Liu, Yang Yang and Fanyang Mo*

Chem. Sci. 2018, 9, 8731-8737. Sep 17 2018

11. Oxidant-free oxidation of C−H bond by cathodic hydrogen evolution: a phosphonic Kolbe oxidation/cyclization process

Lei Zhang, Zhenxing Zhang, Jianning Zhang, Kangle Li and Fanyang Mo*

Green Chem. 2018, 20, 3916-3920. Jul 19 2018

10. Addition of Diazo Compounds ipso-C-H bond to Carbon Disulfide: Synthesis of 1,2,3-Thiadiazoles Under Mild Conditions

Lei Zhang, Beiqi Sun, Qianyi Liu, Fanyang Mo*

J. Org. Chem. 2018, 83, 4275–4278. Mar 19 2018

9. Oxidant-Free C(sp2)−H Functionalization/C−O Bond Formation: A Kolbe Oxidative Cyclization Process

Lei Zhang, Zhenxing Zhang, Junting Hong, Jian Yu, Jianning Zhang, Fanyang Mo*

J. Org. Chem. 2018, 83, 3200–3207. Feb 23 2018

8. Renaissance of Sandmeyer-Type Reactions: Conversion of Aromatic C-N Bonds into C-X Bonds (X = B, Sn, P, CF3)

Fanyang Mo,* Di Qiu, Yan Zhang and Jianbo Wang*

Acc. Chem. Res. 2018, 51, 496-506. Jan 25 2018

7. Cu(I)-Catalyzed Asymmetric Cross-Coupling of N-Tosylhydrazones and Trialkylsilylethynes: Enantioselective Construction of C(sp)-C(sp3) Bonds

Wen-Dao Chu, Fangfang Guo, Lefei Yu, Junting Hong, Qianyi Liu, Fanyang Mo, Yan Zhang and Jianbo Wang*

Chin. J. Chem. 2018, 36, 217-222. Jan 11 2018

2017

6. Direct Carboxylation of the Diazo Group ipso-C(sp2)–H bond with Carbon Dioxide: Access to Unsymmetrical Diazomalonates and Derivatives

Qianyi Liu, Man Li, Rui Xiong and Fanyang Mo*

Org. Lett. 2017, 19, 6756–6759. Dec 6 2017

5. Chapter Two - Recent Advances in Transition-Metal-Catalyzed Cross-Coupling Reactions With N-Tosylhydrazones

Di Qiu, Fanyang Mo, Yan Zhang and Jianbo Wang*

Adv. Organomet. Chem. 2017, 67, 151-219.

2016

4. Enantioselective Synthesis of Trisubstituted Allenes via Cu(I)-Catalyzed Coupling of Diazoalkanes with Terminal Alkynes

Wen-Dao Chu, Lei Zhang, Zhikun Zhang, Qi Zhou, Fanyang Mo, Yan Zhang and Jianbo Wang*

J. Am. Chem. Soc. 2016, 138, 14558–14561.

3. Metal-Free Aromatic Carbon–Phosphorus Bond Formation via a Sandmeyer-Type Reaction

Shuai Wang, Di Qiu, Fanyang Mo, Yan Zhang and Jianbo Wang*

J. Org. Chem. 2016, 81, 11603–11611.

2. Rhodium(I)-Catalyzed C−C Bond Activation of Siloxyvinylcyclopropanes with Diazoesters

Sheng Feng, Fanyang Mo, Ying Xia, Zhenxing Liu, Zhen Liu, Yan Zhang and Jianbo Wang*

Angew. Chem. Int. Ed. 2016, 55, 15401-15405.

2015

1. Bi-functional Ligand-assisted Catalytic Ketone α-Alkenylation with Internal Alkynes: Controlled Synthesis of Enones and Mechanistic Studies

Fanyang Mo, Hee Nam Lee and Guangbin Dong*

J. Am. Chem. Soc. 2015, 137, 15518-15527.

--------------------Prior to PKU faculty--------------------

1. Synthesis, Structure, and Reactivity of Anionic sp2–sp3 Diboron Compounds: Readily Accessible Boryl Nucleophiles

Sabrina Pietsch, Emily C. Neeve, David C. Apperley, Rüdiger Bertermann, Fanyang Mo, Di Qiu, Man Sing Cheung, Li Dang, Jianbo Wang, Udo Radius, Zhenyang Lin, Christian Kleeberg and Todd B. Marder*

Chem. Eur. J. 2015, 21, 7082-7098.

2. Transition metal-catalyzed ketone-directed or mediated C–H functionalization

Zhongxing Huang, Hee Nam Lim, Fanyang Mo, Michael C. Young and Guangbin Dong*

Chem. Soc. Rev. 2015, 44, 7764-7786.

3. Cholate-Based Synthesis of Size-Tunable Cage Compounds

Lingling Peng, Fanyang Mo and Qinghai Zhang*

J. Org. Chem. 2015, 80, 1221-1228.

4. Regioselective ketone α-alkylation with simple olefins via dual activation

Fanyang Mo and Guangbin Dong*

Science 2014, 345, 68-72.

5. Synthesis of Trimethylstannyl Arylboronate Compounds by Sandmeyer-Type Transformations and Their Applications in Chemoselective Cross-Coupling Reactions

Di Qiu, Shuai Wang, Shengbo Tang, He Meng, Liang Jin, Fanyang Mo, Yan Zhang and Jianbo Wang*

J. Org. Chem. 2014, 79, 1979-1988.

6. Alcohols or Masked Alcohols as Directing Groups for C–H Bond Functionalization

Fanyang Mo, John R. Tabor and Guangbin Dong*

Chem. Lett. 2014, 43, 264-271.

7. Recent applications of arene diazonium salts in organic synthesis

Fanyang Mo, Guangbin Dong*, Yan Zhang and Jianbo Wang*

Org. Biomol. Chem. 2013, 11, 1582-1593.

8. Silver-Mediated Trifluoromethylation of Aryldiazonium Salts: Conversion of Amino Group into Trifluoromethyl Group

Xi Wang, Yan Xu, Fanyang Mo, Guojing Ji, Di Qiu, Jiajie Feng, Yuxuan Ye, Songnan Zhang, Yan Zhang and Jianbo Wang*

J. Am. Chem. Soc. 2013, 135, 10330-10333.

9. Synthesis of Aryl Trimethylstannanes from Aryl Amines: A Sandmeyer-Type Stannylation Reaction

Di Qiu, He Meng, Liang Jin, Shuai Wang, Shengbo Tang, Xi Wang, Fanyang Mo, Yan Zhang and Jianbo Wang*

Angew. Chem. Int. Ed. 2013, 52, 11581-11584.

10. Synthesis of Pinacol Arylboronates from Aromatic Amines: A Metal-Free Transformation

Di Qiu, Liang Jin, Zhitong Zheng, He Meng, Fanyang Mo, Xi Wang, Yan Zhang and Jianbo Wang*

J. Org. Chem. 2013, 78, 1923-1933.

11. Studies toward the Synthesis of (R)-(+)-Harmicine

Fanyang Mo, Fei Li, Di Qiu, Yan Zhang and Jianbo Wang*

Chinese J. Chem. 2012, 30, 2297-2302.

12. Synthesis of ortho-Acylphenols through the Palladium-Catalyzed Ketone-Directed Hydroxylation of Arenes

Fanyang Mo, Louis J. Trzepkowski and Guangbin Dong*

Angew. Chem. Int. Ed. 2012, 51, 13075-13079.

13. Catalyst-Free Imidation of Allyl Sulfides with Chloramine-T and Subsequent [2,3]-Sigmatropic Rearrangement

Yubo Jiang, Fanyang Mo, Di Qiu, Chunxiang Kuang, Yan Zhang and Jianbo Wang*

Chinese J. Chem. 2012, 30, 2029-2035.

14. Catalytic Functionalization of Unactivated sp3 C–H Bonds via exo-Directing Groups: Synthesis of Chemically Differentiated 1,2-Diols

Zhi Ren#, Fanyang Mo# and Guangbin Dong*

J. Am. Chem. Soc. 2012, 134, 16991-16994.

15. Increments for 1H and 13C NMR chemical shifts in pinacol arylboronates

Di Qiu, Zhitong Zheng, Fanyang Mo, Yan Zhang and Jianbo Wang*

Can. J. Chem. 2012, 90, 71-74.

16. Gold(III)-Catalyzed Direct Acetoxylation of Arenes with Iodobenzene Diacetate

Di Qiu, Zhitong Zheng, Fanyang Mo, Qing Xiao, Yu Tian, Yan Zhang and Jianbo Wang*

Org. Lett. 2011, 13, 4988-4991.

17. New developments in aromatic halogenation, borylation, and cyanation

Di Qiu, Zhitong Zheng, Fanyang Mo, Yan Zhang and Jianbo Wang*

Chimia 2011, 65, 909-913.

18. A base-free, one-pot diazotization/cross-coupling of anilines with arylboronic acids

Fanyang Mo, Di Qiu, Yubo Jiang, Yan Zhang and Jianbo Wang*

Tetrahedron Lett. 2011, 52, 518-522.

19. Diastereoselective addition of lithium enolate of γ-substituted α-diazoacetoacetate to N-sulfinyl imines

Fanyang Mo, Fei Li and Jianbo Wang*

Chinese. Sci. Bull. 2010, 55, 2847-2854.

20. Gold(III)-Catalyzed Halogenation of Aromatic Boronates with N-Halosuccinimides

Di Qiu, Fanyang Mo, Zhitong Zheng, Yan Zhang and Jianbo Wang*

Org. Lett. 2010, 12, 5474-5477.

21. Enantioselective synthesis of condensed and transannular ring skeletons containing pyrrolidine moiety

Fanyang Mo, Fei Li, Di Qiu and Jianbo Wang*

Tetrahedron 2010, 66, 1274-1279.

22. Direct Conversion of Arylamines to Pinacol Boronates: A Metal-Free Borylation Process

Fanyang Mo, Yubo Jiang, Di Qiu, Yan Zhang and Jianbo Wang*

Angew. Chem. Int. Ed. 2010, 49, 1846-1849.

23. Gold-Catalyzed Halogenation of Aromatics by N-Halosuccinimides

Fanyang Mo, Jerry Mingtao Yan, Di Qiu, Fei Li, Yan Zhang and Jianbo Wang*

Angew. Chem. Int. Ed. 2010, 49, 2028-2032.

24. AuPPh3Cl/AgOTf-catalyzed reaction of terminal alkynes: nucleophilic addition to activated CO bond

Changkun Li, Fanyang Mo, Weibin Li and Jianbo Wang*

Tetrahedron Lett. 2009, 50, 6053-6056.

25. Highly Diastereoselective Addition of the Lithium Enolate of α-Diazoacetoacetate to N-Sulfinyl Imines: Enantioselective Synthesis of 2-Oxo and 3-Oxo Pyrrolidines

Changqing Dong, Fanyang Mo and Jianbo Wang*

J. Org. Chem. 2009, 73, 1971-1974.